Kinetic solvent effects on hydroxylic hydrogen atom abstractions are independent of the nature of the abstracting radical. Two extreme tests using vitamin E and phenol

DOI: 10.1021/ja00145a005

Source and publish data:

Journal of the American Chemical Society p. 9966 - 9971 (1995)

Update date:2022-08-29

Topics:

Authors:

Valgimigli, Luca

Banks Banks

Ingold Ingold

Lusztyk Lusztyk

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00145a005

Rate constants have been measured at 25°C in 13 solvents (S) for abstraction of the phenolic hydrogen atom from α-tocopherol (TOH) by tert-butoxyl (BO^.) k(TOH/BO)(S), and by 2,2-diphenyl-1-picrylhydrazyl (DPPH^.), k(TOH/DPPH)(S), and

Full text of DOI:10.1021/ja00145a005

Products guided by the article

Product name:phenyloxidanyl

Cas No:2122-46-5

R&D Labs maybe for 2122-46-5

Sinonine Industry Co.,Ltd

Contact:86+21-56421993

Address:3F,BUILDING 10,NO.2889 JINKE ROAD, SHANGHAI.
Jiangsu Cale New Material Co.ltd

Contact:+86-515-88334667/88203550

Address:Zhongshan 3rd Road, Coastal Chemical Industry Park, Yancheng, Jiangsu, China
ZHEJIANG PAULA INDUSTRY CO.,LTD

website:http://www.haiqiangchem.com

Contact:86-571-86960380

Address:6th floor, building 2, dongfangmao business center, Xiacheng District, Hangzhou City, Zhejiang Province
Shanghai Yuantai Chemical Products Co., Ltd

Contact:021--66129803

Address:Chengyin Road,Shanghai,China
Shandong LuZhou Amino Acid Co., Ltd

Contact:86-539-2218025

Address:yishui economic and technical development zone zhenxing south road

Relevant to this article

Doi:10.1021/ja01647a039
(1954)
Preparation of recoverable Fe₃O₄@PANI-Pd^II core/shell catalysts for Suzuki carbonylative cross-coupling reactions

Doi:10.1039/c4nj00697f
(2014)
Enhanced singlet oxygen generation of a soft salt through efficient energy transfer between two ionic metal complexes

Doi:10.1039/c8dt00720a
(2018)
SYNTHESIS OF SOME L-IDOSE DERIVATIVES

Doi:10.1007/BF00579627
(1982)
An eco-friendly one-pot synthesis of 4,4′-(arylmethylene)bis(1H-pyrazol-5-ols) using [Et₃NH][HSO₄] as a recyclable catalyst

Doi:10.4067/S0717-97072015000300003
(2015)
Effect of the nature of zeolite and modifying additives on the activity of zeolite-containing catalysts in n-butane isomerization

Doi:10.1007/BF02495288
(1999)

Article Doi