Kinetic solvent effects on hydroxylic hydrogen atom abstractions are independent of the nature of the abstracting radical. Two extreme tests using vitamin E and phenol

DOI: 10.1021/ja00145a005

Source and publish data:

Journal of the American Chemical Society p. 9966 - 9971 (1995)

Update date:2022-08-29

Topics:

Authors:

Valgimigli, Luca

Banks Banks

Ingold Ingold

Lusztyk Lusztyk

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Article abstract of DOI:10.1021/ja00145a005

Rate constants have been measured at 25°C in 13 solvents (S) for abstraction of the phenolic hydrogen atom from α-tocopherol (TOH) by tert-butoxyl (BO^.) k(TOH/BO)(S), and by 2,2-diphenyl-1-picrylhydrazyl (DPPH^.), k(TOH/DPPH)(S), and

Full text of DOI:10.1021/ja00145a005

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