Journal of Physical Chemistry p. 2906 - 2909 (1985)
Update date:2022-08-11
Topics:
Fahr, Askar
Laufer, Allan H.
The primary photodissociation processes in the photolysis of vinyl chloride have been investigated by using the flash photolysis-kinetic spectroscopic technique.Concentrations and temporal profiles of product H2CC(3B2), HCl, and C2H2 are monitored by their absorption in the vacuum ultraviolet at 137, 139, and 151 nm, respectively.HCl and H2CC(3B2) are formed with the same time history via a 1,1 elimination from excited C2H3Cl.Rate constants for the interaction of H2CC(3B2) with He, 1.07 +/= 0.17E-14 cm3 molecule-1 s-1, and C2H3Cl, 3.5E-11 cm3 molecule-1 s-1, have been obtained.
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