TUNNELING PARAMETERS FOR THE HYDROGEN ATOM ABSTRACTION REACTIONS OF DIPHENYLCARBENE IN A LOW TEMPERATURE TOLUENE MATRIX

DOI: 10.1016/S0040-4039(00)86961-0

Source and publish data:

Tetrahedron Letters p. 833 - 836 (1982)

Update date:2022-08-11

Topics:

Authors:

Wright, Bradford B.

Senthilnathan, V. P.

Platz, Matthew S.

McCurdy, C. W.

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Article abstract of DOI:10.1016/S0040-4039(00)86961-0

Tunneling reaction rate constants of diphenylcarbene in a toluene matrix can be fit by an asymmetric Eckart barrier.The barrier heights are in good agreement with theory.

Full text of DOI:10.1016/S0040-4039(00)86961-0

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