SYNTHESIS OF (+/-)-PYRENOPHORIN UTILIZING 1,3-DIPOLAR CYCLOADDITION OF SILYL NITRONATE FOR THE CONSTRUCTION OF 16-MEMBERED RING

DOI: 10.1016/0040-4039(81)80137-2

Source and publish data:

Tetrahedron Letters p. 735 - 738 (1981)

Update date:2022-08-17

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Authors:

Asaoka, Morio

Mukuta, Takashi

Takei, Hisashi

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Article abstract of DOI:10.1016/0040-4039(81)80137-2

1-Methyl-4-nitrobutyl acrylate underwent 1,3-dipolar cycloaddition via its silyl nitronate to give isoxazoline derivative of 16-membered dilactone after acid treatment, from which (+/-)-pyrenophorin was synthesized.

Full text of DOI:10.1016/0040-4039(81)80137-2

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