SYNTHESIS OF (+/-)-PYRENOPHORIN UTILIZING 1,3-DIPOLAR CYCLOADDITION OF SILYL NITRONATE FOR THE CONSTRUCTION OF 16-MEMBERED RING

DOI: 10.1016/0040-4039(81)80137-2

Source and publish data:

Tetrahedron Letters p. 735 - 738 (1981)

Update date:2022-08-17

Topics:

Authors:

Asaoka, Morio

Mukuta, Takashi

Takei, Hisashi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(81)80137-2

1-Methyl-4-nitrobutyl acrylate underwent 1,3-dipolar cycloaddition via its silyl nitronate to give isoxazoline derivative of 16-membered dilactone after acid treatment, from which (+/-)-pyrenophorin was synthesized.

Full text of DOI:10.1016/0040-4039(81)80137-2

Products guided by the article

Product name:5-Nitro-2-pentanone

Cas No:22020-87-7

R&D Labs maybe for 22020-87-7

Jinan Finer Chemical Co., Ltd

website:https://www.finerchem.com

Contact:+86-531-88989536

Address:New Material Industrial Park, Jinan City, China
Chengdu ZY Biochemical Technology Co., LTD

Contact:0086-28-88680086

Address:170 Qingpu Road, Shouan Town, Pujiang County
NanJing KaiHeng Chemical CO., LTD.

Contact:+86-25-85768391

Address:RM.1704, D, WANDA PLAZA, NO.110, MIDDLE JIANGDONG ROAD, NANJING, CHINA
Chuzhou Baiao Biologhy S&T Co., Ltd.

Contact:+86-25-83212599；+86-25-83212699 13705185959

Address:Room 905, Tianzheng International Platza, No.399, Zhongyang Road ,Nanjing, Jiangsu Province, China
Zhushan County Tianxin Pharmaceutical & Chemical Co., Ltd.

Contact:0086-719-4224892

Address:Tutang Road, Chengguan Town, Zhushan County, Hubei Province

Relevant to this article

Synthesis and characterization of novel urea and thiourea substitute cyclotriphosphazene compounds as naked-eye sensors for F- and CN- anions

Doi:10.3906/kim-1502-59
(2015)
Direct and practical synthesis of primary anilines through iron-catalyzed C-H bond amination

Doi:10.1021/acscatal.6b02576
(2016)
The extremely low intrinsic reactivity of the P-(formylmethyl)triphenylphosphonium cation: An artefact due to strong covalent hydration of the carbonyl group

Doi:10.1039/a903667i
(1999)
Chromium vinylidene carbenoids: stereospecific synthesis of (Z)-2-chloroalk-2-en-1-ols.

Doi:10.1021/ol016935h
(2001)
Different nature of the interactions between anions and HAT(CN) ₆: From reversible anion-π complexes to irreversible electron-transfer processes (HAT(CN)₆ = 1,4,5,8,9,12- hexaazatriphenylene)

Doi:10.1021/ja309960m
(2013)
Design and Synthesis of Sulfanilamide Aminophosphonates as Novel Antibacterial Agents towards Escherichia coli

Doi:10.1002/cjoc.202100165
(2021)

Article Doi