SYNTHESIS OF (+/-)-PYRENOPHORIN UTILIZING 1,3-DIPOLAR CYCLOADDITION OF SILYL NITRONATE FOR THE CONSTRUCTION OF 16-MEMBERED RING

DOI: 10.1016/0040-4039(81)80137-2

Source and publish data:

Tetrahedron Letters p. 735 - 738 (1981)

Update date:2022-08-17

Topics:

Authors:

Asaoka, Morio

Mukuta, Takashi

Takei, Hisashi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(81)80137-2

1-Methyl-4-nitrobutyl acrylate underwent 1,3-dipolar cycloaddition via its silyl nitronate to give isoxazoline derivative of 16-membered dilactone after acid treatment, from which (+/-)-pyrenophorin was synthesized.

Full text of DOI:10.1016/0040-4039(81)80137-2

Products guided by the article

Product name:5-Nitro-2-pentanone

Cas No:22020-87-7

R&D Labs maybe for 22020-87-7

Accendatech Co., LTD

Contact:+86-22-83718541

Address:32th Floor, Rongqiao Center Intersection of Changjiang Road and Nankai Six Road Nankai District Tianjin 300102, China
APOLLO HEALTHCARE RESOURCES

Contact:+65 9658 0999

Address:26 Sin Ming Lane, Midview City, #05-118, Singapore 573971
FUJIAN SHANSHUI CHEMICAL CORP.LTD.

Contact:+86-151-59920036

Address:Jinqiao Gareden, jo@fj-xinyi.com
NINGXIA DARONG CHEMICALS & METALLURGY CO.,LTD.

Contact:86-952-2179751

Address:Darong Road, Dawukou, Shizuishan, Ningxia 753001, China
Shanghai Bocimed Pharmaceutical Co., Ltd.

website:http://www.bocimed.com

Contact:+86-21-68861632

Address:Building 1, Lane 647, Songtao Road, Zhangjiang High-Tech Park, Shanghai

Relevant to this article

Synthesis and characterization of novel urea and thiourea substitute cyclotriphosphazene compounds as naked-eye sensors for F- and CN- anions

Doi:10.3906/kim-1502-59
(2015)
Direct and practical synthesis of primary anilines through iron-catalyzed C-H bond amination

Doi:10.1021/acscatal.6b02576
(2016)
The extremely low intrinsic reactivity of the P-(formylmethyl)triphenylphosphonium cation: An artefact due to strong covalent hydration of the carbonyl group

Doi:10.1039/a903667i
(1999)
Chromium vinylidene carbenoids: stereospecific synthesis of (Z)-2-chloroalk-2-en-1-ols.

Doi:10.1021/ol016935h
(2001)
Different nature of the interactions between anions and HAT(CN) ₆: From reversible anion-π complexes to irreversible electron-transfer processes (HAT(CN)₆ = 1,4,5,8,9,12- hexaazatriphenylene)

Doi:10.1021/ja309960m
(2013)
Design and Synthesis of Sulfanilamide Aminophosphonates as Novel Antibacterial Agents towards Escherichia coli

Doi:10.1002/cjoc.202100165
(2021)

Article Doi