Chemistry Letters p. 1839 - 1840 (1985)
Update date:2022-08-29
Topics:
Kurosawa, Hideo
Urabe, Akira
h1-Allyl(aryl)palladium complexes react with some electrophiles to result in the selective Pd-allyl bond cleavage with 1,3-transposition, while the corresponding η3-allyl(aryl)palladiums and the electrophiles give rise to the selective Pd-Ar bond cleavage.The η1-allyl complexes also react with CCl4 and CHCl3 under very mild conditions to give good yields of CH2=CHCHR(CR'Cl2) (R=H, Me; R'=Cl, H).
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