A facile approach to N-unsubstituted phosphinimines

DOI: 10.1055/s-1995-4145

Source and publish data:

Synthesis p. 1496 - 1496 (1995)

Update date:2022-08-11

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Authors:

Hendrickson

Sommer Sommer

Singer Singer

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Article abstract of DOI:10.1055/s-1995-4145

Phosphine oxides (R₃P = O) are conveniently converted into phosphinimines (R₃P = NH) by recycling several times through the sequence: triflic anhydride; ammonia; evaporation. Half of the triflic anhydride is used at each repeat.

Full text of DOI:10.1055/s-1995-4145

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