Journal of Organic Chemistry p. 7557 - 7561 (1993)
Update date:2022-08-11
Topics:
Doxsee, Kenneth M.
Ferguson, Cynthia M.
Wash, Paul L.
Saulsbery, Robin L.
Hope, Hakon
Solution and solid-state structural data are presented for a discrete complex of phenacyl alcohol with calcium chloride, <(C6H5COCH2OH)2Ca(H2O)3>(2+)*2Cl(-)*H2O, in which phenacyl alcohol serves as a bidentate ligand, with coordination of calcium to both the carbonyl oxygen and the hydroxyl group.This constitutes the first structural characterization of a calcium complex with the important pharmacophoric α-hydroxy ketone functionality.
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