Calcium Complexation by α-Hydroxy Ketones. Characterization of a Calcium Complex of Phenacyl Alcohol

DOI: 10.1021/jo00078a040

Source and publish data:

Journal of Organic Chemistry p. 7557 - 7561 (1993)

Update date:2022-08-11

Topics:

Authors:

Doxsee, Kenneth M.

Ferguson, Cynthia M.

Wash, Paul L.

Saulsbery, Robin L.

Hope, Hakon

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Article abstract of DOI:10.1021/jo00078a040

Solution and solid-state structural data are presented for a discrete complex of phenacyl alcohol with calcium chloride, <(C6H5COCH2OH)2Ca(H2O)3>(2+)*2Cl(-)*H2O, in which phenacyl alcohol serves as a bidentate ligand, with coordination of calcium to both the carbonyl oxygen and the hydroxyl group.This constitutes the first structural characterization of a calcium complex with the important pharmacophoric α-hydroxy ketone functionality.

Full text of DOI:10.1021/jo00078a040

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