Rotational isomerism of O,O'-dialkyl esters of phosphorodithioic acid

DOI: 10.1016/0584-8539(88)80061-8

Source and publish data:

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy p. 393 - 398 (1988)

Update date:2022-08-28

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Authors:

Waters, David N.

Paddy, John L.

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Article abstract of DOI:10.1016/0584-8539(88)80061-8

Compounds (RO)2P(:S)SH, R=Prⁱ, Buⁿ, and Octⁿ, exhibit rotational isomerism about P-O and P-S bonds.Temperature-dependence studies of band intensities indicate values of ΔH for the equilibria between isomers to be 2.5 kJ mol^-1, R=Prⁱ; 3.0 kJ mol^-1, R=Buⁿ; and ca. 4.5 kJ mol^-1, R=Octⁿ.

Full text of DOI:10.1016/0584-8539(88)80061-8

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