Journal of the Chemical Society. Chemical communications p. 268 - 269 (1981)
Update date:2022-08-16
Topics:
Hossain, S. Fazley
Nicholas, Kenneth M.
Teas, Carol L.
Davis, Raymond E.
The intermediate produced from the interaction of HRh(CO)(PPh3)3 with CO reacts with carbon dioxide to yield a novel hydrogencarbonate complex, trans-(Ph3P)2Rh(CO)(OCO2H) (1), whose structure has been established by X-ray crystallography; (1) undergoes reversible loss of CO2.
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(1980)
