
Tetrahedron Letters p. 3516 - 3519 (2008)
Update date:2022-08-17
Topics:
Saidi, Ourida
Ruan, Jiwu
Vinci, Daniele
Wu, Xiaofeng
Xiao, Jianliang
The regioselective hydroformylation of enamides with a catalyst derived from monodentate phosphites and Rh(acac)(CO)2 was studied. In the hydroformylation of N-vinylphthalimide, all the biphenol-based ligands led to the branched aldehyde; the fastest reaction was observed when using a sterically bulky phosphite. The olefins (E)-N-propenylphthalimide, vinylpyrrolidone, vinylcaprolactam and vinylcarbazole were also investigated.
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