Bulletin of the Chemical Society of Japan p. 3521 - 3522 (1983)
Update date:2022-08-16
Topics:
Tsuboi, Sadao
Masuda, Toshihide
Takeda, Akira
The total synthesis of (3E,5Z)-3,5-tetradecadienoic acid (megatomoic acid) is accomplished with 74percent stereoselectivity through the use of stereoselective rearrangement of ethyl 3,4-tridecadienoate to ethyl (2E,4Z)-2,4-tridecadienoate with alumina and the extension of the carbon chain with methyl methylthiomethyl sulfone.
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