
Tetrahedron Letters p. 5303 - 5306 (1982)
Update date:2022-08-29
Topics:
Kakinuma, Katsumi
Uzawa, Jun
Uramoto, Masakazu
A mechanism involving contraction of an 18-membered polyketide ring was proposed for the biosynthesis of the 17-membered carbocyclic ring of lankacidin antibiotics based on the feeding experiments of deuterated glycine and (2)H-NMR spectroscopy.
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Doi:10.1016/S0040-4039(00)72362-8
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(1976)