Tetrahedron Letters p. 3383 - 3386 (1994)
Update date:2022-08-16
Topics:
Bonadies, Francesco
Cardilli, Antonella
Lattanzi, Alessandra
Orelli, Liliana R.
Scettri, Arrigo
Aldehydes undergo an efficient E-stereoselective Horner-Wadsworth-Emmons olefination by generation of phosphonate carbanion with lithium hydroxide. The reaction proceeds satisfactorily with linear, cyclic, polifunctional ketones in the presence of activated zeolites and by the slow addition of the base.
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