Kinetic model of radical reaction in plastic crystals

Article abstract of DOI:10.1080/10587259408027172

The kinetic features of diffusion-depended model process of photoinduced nitroxide formation from 2-methyl-2-nitrosopropane in a number of plastic crystals (PC: cyclohexane, cyclohexanol, cyclohexanon, cyclopentanon, 1,1,1-trichlorethane, tert-butylchloride, tert-butylamine, tert-butanol, benzene have been studied by ESR. The kinetic model that relates the nitroxide formation quantum yield with parameters of Lennard - Jones' potentials and thermodynamic properties of PC is proposed.

Full text of DOI:10.1080/10587259408027172

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Molecular Crystals and Liquid Crystals
Science and Technology. Section A.
Molecular Crystals and Liquid Crystals
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The Kinetic Model of Radical Reaction in
Plastic Crystals
Yu. N. Morosov a , T. I. Shabatina a , V. A. Batyuk a & G. B. Sergeev a
a Moscow State University, Chemistry Department , 119899, Moscow,
Russia
Published online: 24 Sep 2006.
To cite this article: Yu. N. Morosov , T. I. Shabatina , V. A. Batyuk & G. B. Sergeev (1994) The
Kinetic Model of Radical Reaction in Plastic Crystals, Molecular Crystals and Liquid Crystals
Science and Technology. Section A. Molecular Crystals and Liquid Crystals, 248:1, 117-123, DOI:
10.1080/10587259408027172
To link to this article: http://dx.doi.org/10.1080/10587259408027172
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