Journal of the Chemical Society. Perkin Transactions 2 (2001) p. 2563 - 2565 (1996)
Update date:2022-08-10
Topics:
Azzena, Ugo
Casado, Francisco
Fois, Pierfrancesco
Gallardo, Iluminada
Pisano, Luisa
Marquet, Jordi
Melloni, Giovanni
The importance of electrostatic effects in the chemical evolution of charged intermediates of the radical anion type is demonstrated. Thus, the regioselectivity of the electron transfer-induced reductive cleavage of alkyl 2,6-diphenylphenyl ethers and alkyl 2,6-dimethoxyphenyl ethers is completely reversed when a positive charge is placed in a controlled manner near the alkyl ether bond.
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