Enantioselective synthesis of (3S,5R,6E,8E)-deca-6,8-dien-1,3,5-triol, a new metabolite from Streptomyces fimbriatus via asymmetric reaction of diketene with 2,4-hexadienal promoted by chiral Schiff base-titanium alkoxide complexes

DOI: 10.1016/0957-4166(95)00328-M

Source and publish data:

Tetrahedron Asymmetry p. 2511 - 2516 (1995)

Update date:2022-08-24

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Authors:

Hayashi Hayashi

Kaneda Kaneda

Oguni Oguni

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Article abstract of DOI:10.1016/0957-4166(95)00328-M

(3S,5R,6E,8E)-deca-6,8-dien-1,3,5-triol, 6 which was isolated from the culture filtrate of Streptomyces fimbriatus has been synthesized efficiently via the enantioselective reaction of diketene with 2,4-hexadienal promoted by a novel chiral Schiff base-titanium alkoxide complex.

Full text of DOI:10.1016/0957-4166(95)00328-M

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