Tetrahedron Letters p. 8765 - 8768 (1998)
Update date:2022-08-24
Topics:
Smith III, Amos B.
Cho, Young Shin
Friestad, Gregory K.
A modification of the Wacker oxidation of terminal olefins to methyl ketones using substoichiometric amounts of Cu(OAc)2 as a redox shuttle reagent is described. The modified procedure is generally high yielding despite reduced levels of copper salt and convenient. Importantly, in a problematic case, the conditions suppressed acidic hydrolysis during oxidation of substrate (+)-5 containing an acetonide.
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