Fluoride-induced Activation of Molybdenum Hexacarbonyl: Formation of Esters and Lactones from Alkyl Iodides

DOI: 10.1039/c39920001678

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1678 - 1679 (1992)

Update date:2022-08-28

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Authors:

Imbeaux, Michele

Mestdagh, Helene

Moughamir, Khadija

Rolando, Christian

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Article abstract of DOI:10.1039/c39920001678

In the presence of fluoride ion, alkyl iodides RI are carbonylated by molybdenum hexacarbonyl to esters RCO2R, and diiodides lead to good yields of the corresponding lactones.

Full text of DOI:10.1039/c39920001678

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