Chemical Communications p. 2627 - 2628 (1996)
Update date:2022-08-17
Topics:
Inoue, Yoshihisa
Tsuneishi, Hiroshi
Hakushi, Tadao
Yagi, Kazutoshi
Awazu, Koichi
Onuki, Hideo
A newly developed polarizing undulator installed in a storage ring was employed for the first time as a source of circularly polarized synchrotron radiation in the vacuum ultraviolet to effect enantiodifferentiating direct photoisomerization of (E)-cyclooctene; the photolysis is taken as a terrestrial mimic or proof of extraterrestrial absolute asymmetric synthesis on interstellar grains by the polarized synchrotron radiation from fast electrons orbiting a neutron star, which is thought to be a distant origin of the homochirality in the biosphere.
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Doi:10.1021/jo00913a008
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