Sodium methylthiolate as an efficient deprotecting agent for dicobalt hexacarbonyl complexes of acetylenes

DOI: 10.1016/S0040-4039(99)01643-3

Source and publish data:

Tetrahedron Letters p. 7749 - 7752 (1999)

Update date:2022-08-28

Topics:

Authors:

Davis, D. Scott

Shadinger, Sylvia C.

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Article abstract of DOI:10.1016/S0040-4039(99)01643-3

Various dicobalt hexacarbonyl acetylene complexes were efficiently converted to the unprotected acetylene by the reaction of two molar equivalents of sodium methylthiolate. Yields and reaction times depend upon the choice of solvent. DMF proved to be the

Full text of DOI:10.1016/S0040-4039(99)01643-3

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