Tetrahedron p. 345 - 350 (1987)
Update date:2022-08-11
Topics:
Al-Lohedan, Hamad A.
The reaction of hydroxide ion with methyl N-alkyl-N,N-dimethylglycinate (1) is catalysed by cationic micelles.The variation of the first-order constant, kψ, with the concentration of CTACl can be fitted to the pseudophase ion-exchange model, but this model fails when the counterion of the surfactant is OH(1-).The variations of kψ with counterion of CTAOH fit a kinetic model in which the distribution of the OH(1-) between the aqueous and micellar pseudophase depends upon
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