THE INTERACTION OF ELECTROPHILIC SILANES (Me3SiX, X= ClO4, I, CF3SO3, Br, Cl) WITH NUCLEOPHILES. THE NATURE OF SILYLATION MIXTURES IN SOLUTION.

DOI: 10.1016/S0040-4039(00)98309-6

Source and publish data:

Tetrahedron Letters p. 3403 - 3406 (1985)

Update date:2022-08-24

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Authors:

Bassindale, Alan R.

Stout, Tim

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Article abstract of DOI:10.1016/S0040-4039(00)98309-6

Silanes, Me3SiX, and Nucleophiles, Nu, form 1:1 salts, Me3SiNu(1+)*X(1-) in solution.The effect of both nucleophile and silane on salt formation has been studied, and the implications for the design of more efficient silylation mixtures are discussed.

Full text of DOI:10.1016/S0040-4039(00)98309-6

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