A new thionation reagent: Preparation of primary thioamides from nitriles

Article abstract of DOI:10.1080/00397919208021604

Phosphorus decasulfide reacts with sodium sulfide (1:1 ratio) in tetrahydrofuran at 25°C to afford an in situ reagent 1C (5 eq.) that rapidly converts nitriles into thioamides at 20°C.

Full text of DOI:10.1080/00397919208021604

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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A New Thionation Reagent:
Preparation of Primary
Thioamides from Nitriles
a
Denis Brillon
a
Institut Armand-Frappier, Université du Québec,
531 Boul. Des Prairies Laval, P., Québec, Canada,
H7N 4Z3
Published online: 23 Sep 2006.
To cite this article: Denis Brillon (1992) A New Thionation Reagent: Preparation of
Primary Thioamides from Nitriles, Synthetic Communications: An International Journal
for Rapid Communication of Synthetic Organic Chemistry, 22:10, 1397-1401
To link to this article: http://dx.doi.org/10.1080/00397919208021604
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