Bulletin of the Chemical Society of Japan p. 3345 - 3346 (1984)
Update date:2022-08-10
Topics:
Inoue
Ohtsuka
Hashimoto
A novel reaction involving allene and water took place using palladium(0)-triphenylphosphine as a catalyst in the presence of carbon dioxide to yield 3-methyl-2-methylene-3-buten-1-ol, selectively. A related reaction of allene with methanol or ethanol was found to occur without carbon dioxide.
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