Russian Chemical Bulletin p. 1002 - 1003 (1994)
Update date:2022-08-11
Topics:
Pashkevich, K. I.
Khomutov, O. G.
Filyakova, V. I.
Kuchin, A. V.
Asymmetric polyfluorinated ketones RFCOR are formed by treating various derivatives of (polyfluoro)alkanoic acids (esters, anhydrides, acid chlorides) with lithium tetraalkylaluminates ("ate-complexes").The highest yields of the ketones (65 - 78percent) were obtained from (polyfluoro)alkanoyl chlorides. - Key words: fluorinated ketones, synthesis; lithium tetraalkylaluminates, reaction with (polyfluoro)alkanoyl chlorides.
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