26902-68-1

Basic information

• Product Name: 1,1,1-trifluorodecan-2-one
• Synonyms: 2-decanone, 1,1,1-trifluoro-
• CAS NO: 26902-68-1
• Molecular Formula: C₁₀H₁₇F₃O
• Molecular Weight: 210.2366
• Mol File: 26902-68-1.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 199.6°C at 760 mmHg
• Flash Point: 108.2°C
• Density: 1.015g/cm³
• Vapor Pressure: 0.339mmHg at 25°C
• Refractive Index: 1.387
• CAS DataBase Reference: 1,1,1-trifluorodecan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,1-trifluorodecan-2-one(26902-68-1)
• EPA Substance Registry System: 1,1,1-trifluorodecan-2-one(26902-68-1)

Safety Data

• Hazardous Substances Data: 26902-68-1(Hazardous Substances Data)

Upstream product

• 354-32-5 trifluoracetyl chloride 
• 111-83-1 1-bromo-octane 
• 383-63-1 ethyl trifluoroacetate, 
• 17049-49-9 octylmagnesium bromide 
• 104863-67-4 N-methoxy-N-methyltrifluoroacetamide 
• 193202-41-4 1,1,1-Trifluoro-decan-2-one O-benzyl-oxime 
• 629-27-6 1-Iodooctane 
• 34009-05-7 (octane-1-sulfonyl)-benzene 
• 853569-39-8 3-benzenesulfonyl-1,1,1-trifluoro-decan-2-one 
• 193202-52-7 1-Trifluoromethyl-nonylamine 
• 76-05-1 trifluoroacetic acid 
• 2923-17-3 lithium trifluoroacetate 
• 407-25-0 trifluoroacetic anhydride 
• 123-29-5 ethyl pelargonate 

Downstream Products

• 193202-41-4 1,1,1-Trifluoro-decan-2-one O-benzyl-oxime 
• 111423-27-9 (S)-(-)-(1-trifluoromethyl)nonanol 
• 108535-33-7 (R)-(+)-1,1,1-trifluoro-2-decanol 

Relevant articles and documents

Synthesis of polyfluorinated ketones via ate-complexes

Asymmetric polyfluorinated ketones RFCOR are formed by treating various derivatives of (polyfluoro)alkanoic acids (esters, anhydrides, acid chlorides) with lithium tetraalkylaluminates ("ate-complexes").The highest yields of the ketones (65 - 78percent) were obtained from (polyfluoro)alkanoyl chlorides. - Key words: fluorinated ketones, synthesis; lithium tetraalkylaluminates, reaction with (polyfluoro)alkanoyl chlorides.

A new, practical and efficient sulfone-mediated synthesis of trifluoromethyl ketones from alkyl and alkenyl bromides

We report herein a new and efficient method to prepare trifluoromethyl ketones from the corresponding bromides through sulfones in good yields.

A convenient preparative method for α-trifluoromethyl amines

α-Trifluoromethyl amines (IV) were prepared in three steps: preparation of α-trifluoromethyl ketones (I), their conversion to benzyloximes (II), and reduction of the oximes (II) with lithium aluminium hydride and sodium methoxide. For example, α-trifluoromethyltridecylamine was obtained from the reduction of trifluoromethyl dodecyl ketone benzyl oxime. Elsevier Science S.A.