Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy p. 751 - 756 (1984)
Update date:2022-08-11
Topics:
Sudha, L. V.
Sathyanarayana, D. N.
Several N,N'-arylalkyl thioureas were examined with 1H-NMR and i.r. spectra in order to study the conformation of the -NHCSNH- group.The influence of temperature and substituents on the chemical shift of the N-H protons has been investigated.Formation of a strong intramolecular hydrogen bond stabilizes the trans-cis conformation for most systems, while for the others the prevalence of different rotational isomers can be postulated.The influence of the steric effect on hydrogen bonding and molecular conformation is discussed.
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