Studies on Copper(II) Complexes of ortho-Quinone Mono-oximes: Reaction of Bis(4-chloro-1,2-benzoquinone 2-oximato)copper(II) with Dimethyl Acetylenedicarboxylate under Various Experimental Conditions

DOI: 10.1039/DT9840001461

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1461 - 1462 (1984)

Update date:2022-08-11

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Authors:

Castellani, Carla Bisi

Millini, Roberto

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Article abstract of DOI:10.1039/DT9840001461

In anhydrous methanol the title complex reacts with dimethyl acetylenedicarboxylate to give methyl 5-chloro-1,3-benzoxazole-2-carboxylate instead of 6-chloro-4-hydroxy-2,3-dimethoxycarbonyl-1,4-benzoxazine as in aqueous solution.The role of water in such

Full text of DOI:10.1039/DT9840001461

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