The synthesis of long chain dialkylalkynes, dialkyldiynes and their hydrogenation to monoenes and dienes

Article abstract of DOI:10.1080/00397919808006830

Long methylenic chain dialkylalkynes have been synthesised in high yield by an improved procedure. The methodology has been extended to nonconjugated diynes. Catalytic hydrogenation with a poisoned palladium catalyst affords cis-monoenes and cis, cis-dienes respectively. An improved synthesis of cis- 9-tricosene is described.

Full text of DOI:10.1080/00397919808006830

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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The Synthesis of Long Chain
Dialkylalkynes, Dialkyldiynes
and Their Hydrogenation to
Monoenes and Dienes
I. G. Fisher a & J. H. P. Tyman a
a Department of Chemistry , Brunel University ,
Uxbridge, Middlesex, UB8 3PH, UK
Published online: 22 Aug 2006.
To cite this article: I. G. Fisher & J. H. P. Tyman (1998) The Synthesis of Long Chain
Dialkylalkynes, Dialkyldiynes and Their Hydrogenation to Monoenes and Dienes,
Synthetic Communications: An International Journal for Rapid Communication of
Synthetic Organic Chemistry, 28:8, 1323-1338, DOI: 10.1080/00397919808006830
To link to this article: http://dx.doi.org/10.1080/00397919808006830
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