Journal of Fluorine Chemistry p. 227 - 242 (1982)
Update date:2022-08-17
Topics:
Johri, Kamalesh K.
Katsuhara, Yutaka
DesMarteau, Darryl D.
Substitutive electrophilic dehalogenation reactions of CF3SO2OX (X=Cl,Br) are reported with some covalent inorganic chlorides. These reactions result in the formation of XX′(X,X′Cl,Br) and several new trifluoromethanesulfonate derivatives in excellent yields. Chlorine(I) trifluoromethanesulfonate also oxidatively adds to unsaturated inorganic substrates such as CO, SO2 and SF4 forming new compounds. The reactivity of CF3SO2OCl is rather similar to that of FSO2OBr and some comparisons between the two are given.
View MoreContact:852-27701081
Address:Room 2509, New Tech Plaza, 34 Tai Yau St., San Po Kong, HK
website:http://www.amadischem.com
Contact:86-571-89925085
Address:Watts Cosine.No.166.Xiangmao Road.
Contact:+86-13666670345
Address:Agricultural Development Zone, Haining, Jiaxing, Zhejiang
Fujian Wanke Pharmaceutical Co., LTD.
Contact:+86-598-5026002
Address:Economic development zone,jiangle county
Henan Tianfu Chemical Co., Ltd.
website:http://www.tianfuchem.com
Contact:86-371-55170693/55170694
Address:Zhengzhou International Trade New Territory,Jinshui District,Zhengzhou ,China
Doi:10.1002/asia.201601198
(2017)Doi:10.1039/c39840000867
(1984)Doi:10.1016/j.ejmech.2013.04.067
(2013)Doi:10.1021/acs.inorgchem.8b00763
(2018)Doi:10.1021/j100339a051
(1989)Doi:10.1016/j.jinorgbio.2012.09.017
(2012)