Chemistry Letters p. 81 - 82 (1999)
Update date:2022-08-11
Topics:
Kojima, Takahiko
Matsuda, Yoshihisa
A bis-μ-chloro Ru(II) dimer with tris(2-pyridylmethyl)amine (TPA) exhibited catalytic oxygenation of alkenes and cooxygenation of alkanes in the presence of cyclohexene with molecular oxygen (latm) at room temperature without reducing reagents; reactions proceeded via a radical chain mechanism as a main pathway.
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