Tetrahedron Letters p. 4345 - 4348 (1985)
Update date:2022-08-17
Topics:
Habermehl, Gerhard G.
Hammann, Peter E.
Elimination of a 12α-methanesulfoxy group in 3β-acetoxy-14β-hydroxy-12α-mesyloxy-5β-androstane-17β-carboxylic-acid-14β-lactone under preventing Wagner-Meerwein rearrangements by steric fixation, is reported.Furthermore, the synthesis of this compound and the different elimination behaviors in the 12α- and the 12β-isomers are described.
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