Chemistry Letters p. 1167 - 1168 (1997)
Update date:2022-08-11
Topics:
Sumiyoshi, Takashi
Wu, Feng
Shindo, Toshihiko
Ueta, Syohei
Sawamura, Sadashi
The photochemistry of 9-xanthenyl radicals produced by pulse radiolysis of xanthene in 1,2-dichloroethane (1,2-DCE) and CCl4 was studied by means of successive laser flash photolysis. Photobleaching due to chlorine atom transfer from solvents to the excited 9-xanthenyl radical was observed with quantum yields of 0.04 and 0.29 in 1,2-DCE and CCl4, respectively.
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