A convenient synthesis of glycals employing in-situ generated Cp2TiCl

DOI: 10.1016/S0040-4039(99)01266-6

Source and publish data:

Tetrahedron Letters p. 6087 - 6090 (1999)

Update date:2022-08-11

Topics:

Authors:

Hansen, Thomas

Krintel, Sussie L.

Daasbjerg, Kim

Skrydstrup, Troels

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Article abstract of DOI:10.1016/S0040-4039(99)01266-6

Reductive elimination of acetylated glycosyl bromides to the corresponding glycal is easily achieved by mixing the bromide with Cp₂TiCl₂ and Mn in THF, and hence does not require the separate preparation of Cp₂TiCl using glove-box techniques.

Full text of DOI:10.1016/S0040-4039(99)01266-6

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