Mild, regiospecific hydrocarboxylation of alkynes catalyzed by nickel cyanide under phase transfer conditions

DOI: 10.1016/0022-328X(90)85154-Q

Source and publish data:

Journal of Organometallic Chemistry p. 573 - 577 (1990)

Update date:2022-08-12

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Authors:

Amer, Ibrahim

Alper, Howard

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Article abstract of DOI:10.1016/0022-328X(90)85154-Q

Phase transfer catalyzed reaction of alkynes (e.g., phenylacetylene) with carbon monoxide, aqueous base, toluene as the organic phase, and catalytic amounts of nickel cyanide as the metal catalyst and cetyltrimethylammonium bromide as the phase transfer agent, affords unsaturated acids (e.g., atropic acid) in reasonable yields.This regiospecific reaction occurs under mild conditions.

Full text of DOI:10.1016/0022-328X(90)85154-Q

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