PHOTOADDITION OF ADAMANTYLIDENEADAMANTANE IN THE PRESENCE OF TETRACYANOETHYLENE. a NEW PHOTOEPOXIDATION PROCESS

DOI: 10.1246/cl.1984.1677

Source and publish data:

Chemistry Letters p. 1677 - 1680 (1984)

Update date:2022-08-11

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Authors:

Akaba, Ryoichi

Sakuragi, Hirochika

Tokumaru, Katsumi

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Article abstract of DOI:10.1246/cl.1984.1677

Irradiation of a dichloromethane solution of adamantylideneadamantane in the presence of tetracyanoethylene with bubbling oxygen through a pyrex filter by a 650-W tungsten-halogen lamp gave a high yield (84percent) of the corresponding epoxide.A reasonable mechanism for the efficient epoxidation will be described.

Full text of DOI:10.1246/cl.1984.1677

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