
Tetrahedron Letters p. 3503 - 3506 (1985)
Update date:2022-08-11
Topics:
Cameron, Andrew G.
Knight, David W.
A stereospecific route to cis-2,2-dimethyl-3-alkenyl-cyclopropanecarboxylic Acids is illustrated by a total synthesis of (+/-)-cis-Chrysanthemic Acid (11).The key step consists of an alicyclic Claisen rearrangement of O-silyl enolates derived from appropriately substituted (Z)-4-hexen-6-olides
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Doi:10.1002/jps.2600770206
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