Tetrahedron Letters p. 3897 - 3900 (1995)
Update date:2022-08-10
Topics:
Gimisis, T.
Ballestri, M.
Ferreri, C.
Chatgilialoglu, C.
Boukherroub, R.
Manuel, G.
The deoxygenation of secondary alcohols via thionoesters with the use of 5,10-dihydrosilanthrene as the radical reducing agent has been studied in detail.The ability of hydrogen donation of this silane has been measured using the one-carbon ring expansion of 1-(2-oxocyclopentyl)ethyl radical as a timing device.
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