Integrated infrared intensities and atomic polar tensors in fluoroform

Article abstract of DOI:10.1063/1.440079

The integrated intensities of the fundamental modes in HCF3 and DCF3 have been measured by Wilson-Wells-Penner-Weber method, and the atomic polar tensors were derived.The effective atomic charge for fluorine was found to be χ_F/e=0.598+/-0.018, in good agreement with that in other fluorocarbons.The effective atomic charge for hydrogen was found to be χ_H/e=0.049+/-0.006, a value somewhat lower than that found in other hydrocarbons and their derivatives.

Full text of DOI:10.1063/1.440079

Integrated infrared intensities and atomic polar tensors in fluoroform
Kwan Kim and W. T. King
Citation: The Journal of Chemical Physics 73, 5591 (1980); doi: 10.1063/1.440079
View online: http://dx.doi.org/10.1063/1.440079
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/73/11?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
69.166.47.144 On: Sun, 23 Nov 2014 23:08:57

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
69.166.47.144 On: Sun, 23 Nov 2014 23:08:57

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
69.166.47.144 On: Sun, 23 Nov 2014 23:08:57

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
69.166.47.144 On: Sun, 23 Nov 2014 23:08:57

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
69.166.47.144 On: Sun, 23 Nov 2014 23:08:57

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
69.166.47.144 On: Sun, 23 Nov 2014 23:08:57

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
69.166.47.144 On: Sun, 23 Nov 2014 23:08:57

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
69.166.47.144 On: Sun, 23 Nov 2014 23:08:57