Infrared laser kinetic spectroscopy of a photofragment CS generated by photodissociation of CS2 at 193 nm: Nascent vibrational-rotational- translational distribution of CS

Article abstract of DOI:10.1063/1.451950

Carbon monosulfide fragments generated by CS2 photodecomposition at 193 nm were examined by time-resolved observation of their vibration-rotation spectral lines with infrared diode laser kinetic spectroscopy.The CS molecules were found to be initially spread over a wide range of vibrational and rotational levels which were accessible with available energy, for both the triplet and singlet channels leading to sulfur atoms in the ³P ground and ¹D excited states, respectively.The analysis of the observed line shape has allowed us to obtain information also on translational energy of CS fragments and to distinguish the contributions of the two channels.The branching ratio was thus estimated to be approximately one to one.

Full text of DOI:10.1063/1.451950

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Infrared laser kinetic spectroscopy of a photofragment CS generated by
photodissociation of CS2 at 193 nm: Nascent vibrational–rotational–translational
distribution of CS
Hideto Kanamori and Eizi Hirota
Citation: The Journal of Chemical Physics 86, 3901 (1987); doi: 10.1063/1.451950
View online: http://dx.doi.org/10.1063/1.451950
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/86/7?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
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Evaluation Only. Created with Aspose.PDF. Copyright 2002-2021 Aspose Pty Ltd.
This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
130.70.241.163 On: Sat, 20 Dec 2014 07:40:20

Evaluation Only. Created with Aspose.PDF. Copyright 2002-2021 Aspose Pty Ltd.
This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
130.70.241.163 On: Sat, 20 Dec 2014 07:40:20

Evaluation Only. Created with Aspose.PDF. Copyright 2002-2021 Aspose Pty Ltd.
This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
130.70.241.163 On: Sat, 20 Dec 2014 07:40:20