Bulletin of the Chemical Society of Japan p. 2089 - 2090 (1980)
Update date:2022-08-17
Topics:
Nomiya, Kenji
Sugaya, Yoshio
Sasa, Sadayoshi
Miwa, Makoto
12-Heteropolymolybdic acid, a heteropolyacid of Keggin-structure, behaves as an effective catalyst of the Friedel-Crafts-type reactions for aromatic compounds, such as alkylation by benzyl chloride and t-butyl chloride, acylation by acetyl chloride, and sulfonylation by tosyl chloride.The catalyst mainly gives para-substiuted products for phenol and anisole.The reactions proceed via carbocation-generation mechanism brought about by the strong Broensted acid.
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