Journal of the Chemical Society. Perkin Transactions 2 (2001) p. 217 - 220 (1996)
Update date:2022-08-16
Topics:
Pletcher, Derek
Slevin, Louise
The presence in the medium of free MgII leads to a complete change in the voltammetry for the reduction of 2-acetylnaphthalene in DMF-Bu4NBF4 saturated with carbon dioxide. The mechanism for these changes has been investigated and it is confirmed that the Mg II interacts with the radical anions formed in the initial electron transfer reaction. The relevance of these conclusions to electrocarboxylations carried out in undivided cells with a sacrificial Mg anode is discussed. It is concluded that all the MgII formed at the anode is complexed strongly by the final carboxylated products from the cathode reaction and therefore the cathode reaction occurs in an environment where no free MgII ions are available. On the other hand, the complexation of the carboxylated products stabilises them to unwanted further reactions, thereby improving the selectivity of the electrosynthesis.
View MoreTaimai Sanluck Pharmaceutical Co.,Ltd
Contact:86-592-7662921
Address:8D,No.186,Huarong Road,Huli,Xiamen,China
JIANGXI AIFEIMU TECHNOLOGY CO.,LTD
Contact:+86-570-6040289
Address:FINECHEMICAL PARK,ZIBU TOWN,WANNIAN COUNTY,JIANGXI PROV.,CHINA,ZIP
Shenzhen Feiming Science and Technology Co,. Ltd
Contact:+86-755-85232577
Address:#B2309, Fenglin International Center ,Jixiang Road, Longcheng street, LongGang District, Shenzhen city, Guangdong province, China.
Beijing Huikang Boyuan Chemical Tech Co.,LTD
Contact:+86-10-68862197
Address:No.7 Haiying Road,Science City,Fengtai District,Beijing,China
Contact:+86-371-55981030
Address:Room 1571, Macalline Soho, No.1, Shangdu Road, Zhengzhou, Henan
Doi:10.1016/0040-4039(96)01736-4
(1996)Doi:10.1016/j.tetlet.2013.05.097
(2013)Doi:10.1039/c5tb00340g
(2015)Doi:10.1021/np400585t
(2013)Doi:10.1016/S0022-328X(00)92568-3
(1980)Doi:10.1080/17415993.2017.1391813
(2018)