Journal of Organometallic Chemistry p. 97 - 104 (1980)
Update date:2022-08-16
Topics:
Sonnek, Georg
Reinheckel, Heinz
Pasynkiewicz, S.
Boleslawski, M.
Dluzniewski, T.
Hexyne-1 reacts with dialkylaluminium hydride to give the geminal organodialuminium hexane IIa,b in 80 to 85percent yield.IIa,b form complexes with amines at molar ratios 1:1 as well as 1:2.The properties of the amines, especially steric properties, determine whether a complex is formed and at which molar ratio.
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