Journal fur Praktische Chemie - Chemiker-Zeitung p. 181 - 184 (1993)
Update date:2022-08-16
Topics:
Paetzold, E.
Oehme, G.
Water soluble palladium(II) complexes of the type PdCl2(phosphine)2 with sulfonated phosphines as ligands catalyse the reductive dehalogenation of allyl or benzyl halogenides by means of formates in a biphasic water/heptane system.This reaction can be promoted by addition of polyethers of different types as phase transfer catalysts.Enhancement of reaction rate and control of selectivity are investigated in the reductive conversion of (E)-Ph-CH=CHCH2Cl leading to (E)-Ph-CH=CH-CH3 and Ph-CH2-CH=CH2.
View More
Suzhou Chiral Pharmaceuticals Co., Ltd.
Contact:86-0512-63197058
Address:Building A, No. 2358, Chang'an Road, Wujiang Science Park
Guangzhou Probig Fine Chemical Co., Ltd.
Contact:020-86297874
Address:No.2, 1/F, No.20, Hetai Road,Hebian Village, Baiyun District,Guangzhou,China
website:http://www.greenutra.cn
Contact:0086-411-39553357
Address:No. 7-1-1802, Huizhi Garden,Ocean Square,Dalian, 116033, China
Contact:+44 (0)161 367 9441
Address:
CGeneTech (Suzhou, China) Co., Ltd.
Contact:+86-512-62956962
Address:Room 101，Bld C11,218 Xinghu Rd.,Suzhou industrial Park
Doi:10.1039/c8ta09439j
(2019)Doi:10.1002/jlac.198219820216
(1982)Doi:10.3390/molecules19079215
(2014)Doi:10.1016/j.carres.2010.10.004
(2010)Doi:10.1021/acs.jafc.5b00399
(2015)Doi:10.1016/0022-1902(71)80167-7
(1971)
