Intramolecular ene reaction of vinylphosphonates. Synthetic application to bicyclic compounds and cadalane and valerenic acid terpenoids

DOI: 10.1021/jo00101a034

Source and publish data:

Journal of Organic Chemistry p. 6717 - 6727 (1994)

Update date:2022-08-11

Topics:

Authors:

Minami Minami

Utsunomiya

Nakamura

Okubo Okubo

Kitamura

Okada Okada

Ichikawa

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Article abstract of DOI:10.1021/jo00101a034

The Lewis-acid-catalyzed intramolecular ene reaction of vinylphosphonates 4, 6, and 7, prepared by the Knoevenagel condensation of triethyl phosphonoacetate (3) with citronellal (1) or 2,6-dimethyl-5-heptenal (2), stereoselectively gave 2-(8'-p-menthen-3'

Full text of DOI:10.1021/jo00101a034

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