Intramolecular ene reaction of vinylphosphonates. Synthetic application to bicyclic compounds and cadalane and valerenic acid terpenoids

DOI: 10.1021/jo00101a034

Source and publish data:

Journal of Organic Chemistry p. 6717 - 6727 (1994)

Update date:2022-08-11

Topics:

Authors:

Minami Minami

Utsunomiya

Nakamura

Okubo Okubo

Kitamura

Okada Okada

Ichikawa

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00101a034

The Lewis-acid-catalyzed intramolecular ene reaction of vinylphosphonates 4, 6, and 7, prepared by the Knoevenagel condensation of triethyl phosphonoacetate (3) with citronellal (1) or 2,6-dimethyl-5-heptenal (2), stereoselectively gave 2-(8'-p-menthen-3'

Full text of DOI:10.1021/jo00101a034

Products guided by the article

Product name:1,2,3,4-Tetrahydro-2,5,8-trimethylnaphthalene

Cas No:30316-17-7

R&D Labs maybe for 30316-17-7

Ningbo Tide Imp. & Exp. Co., Ltd.

Contact:+86-571-8993 7933; +86-571-8993 6453

Address:7/F Anno Domini Building, Tower South, 8 Qiu Shi Road,Hangzhou,China.
shijiazhuang alkay chemicals co..ltd(expird)

Contact:86-311-67692035

Address:2601,juntang building,qiaodong district,shijiazhuang
Langchem

Contact:+86+21-58956006 15800617331

Address:402 Room, 150# Cailun Road, Zhangjiang high tech park, Shanghai
WEIFANG RICHEM INTERNATIONAL LTD

Contact:86-536-2222176

Address:weifang,shandong
Suzhou JMS Chemical Co., Ltd.

Contact:+86-15995924277

Address:WuZhongOu suzhou new south road 89

Relevant to this article

Three-Coordinate Iron(0) Complexes with N-Heterocyclic Carbene and Vinyltrimethylsilane Ligation: Synthesis, Characterization, and Ligand Substitution Reactions

Doi:10.1021/acs.inorgchem.9b02009
(2019)
Analysis of substituent effects on C-13 NMR parameters of substituted arylacetylene derivatives. Linear free energy relationships and PM3 semiempirical calculations

Doi:10.1016/S0040-4020(00)00920-0
(2000)
Doi:10.1002/hlca.19520350112
(1952)
Enantioselective catalytic reduction of ketones using C₂-symmetric diamines as chiral ligands

Doi:10.1016/S0040-4039(00)91824-0
(1993)
Copper-Catalyzed Perfluoroalkylation of Allyl Phosphates with Stable Perfluoroalkylzinc Reagents

Doi:10.1021/acs.joc.8b02432
(2019)
Synthesis of 6-methoxy-4H-1-benzopyran-7-ol, a character donating component of the fragrance of Wisteria sinensis

Doi:10.1016/S0040-4020(02)00081-9
(2002)

Article Doi