Nucleophilic Displacement of Bis(perfluoroalkanoyl) Peroxides with Perfluoroalkanoate

Article abstract of DOI:10.1246/bcsj.62.2416

Bis(perfluoroalknoyl) peroxide ((R_FCO2)2) suffered a nucleophilic displacement with perfluoroalkanoate (R_F'CO2(1-)) to give new mixed peroxide (R_F(CO)OO(CO)R_F').When thiophene was reacted with bis(perfluoroalkanoyl) peroxide in the presence of pyridinium perfluoroalkanoate, not only the perfluoroalkyl group (R_F) of the peroxide, but also perfluoroalkyl group (R_F') of perfluoroalkanoate, was introduced into thiophene.