Bulletin of the Chemical Society of Japan p. 2416 - 2418 (1989)
Update date:2022-08-16
Topics:
Yoshida, Masato
Sasage, Shyuichi
Kamigate, Nobumasa
Sawada, Hideo
Nakayama, Masaharu
Bis(perfluoroalknoyl) peroxide ((RFCO2)2) suffered a nucleophilic displacement with perfluoroalkanoate (RF'CO2(1-)) to give new mixed peroxide (RF(CO)OO(CO)RF').When thiophene was reacted with bis(perfluoroalkanoyl) peroxide in the presence of pyridinium perfluoroalkanoate, not only the perfluoroalkyl group (RF) of the peroxide, but also perfluoroalkyl group (RF') of perfluoroalkanoate, was introduced into thiophene.
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