Journal of Organic Chemistry p. 4027 - 4028 (1994)
Update date:2022-08-16
Topics:
Cho, In Sik
Alper, Howard
The binuclear palladium complex, <((t-Bu)2PH)PdP(Bu-t)2>2, when treated with oxygen, catalyzes the hydrogenation of the double bond of α,β-unsaturated sulfones and phosphonates in THF at room temperature and 1 atm of hydrogen pressure.Saturated sulfones and phosphonates were isolated in 49-93percent yields.
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