Journal of the Chemical Society. Chemical communications p. 905 - 906 (1984)
Update date:2022-08-10
Topics:
Alper, Howard
Hartstock, Frederick W.
Despeyroux, Bertrand
Allene undergoes alkoxy-alkoxycarbonylation under exceedingly mild conditions (CO-O2-MeOH-PdCl2-CuCl2, 0 deg C, 1 atm) affording methyl 2-methoxymethylacrylate in good yield; in the case of 1,1-disubstituted allenes the reaction is regiospecific although
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