Journal of the Chemical Society. Chemical communications p. 57 - 58 (1995)
Update date:2022-08-29
Topics:
Fernandez, Jose M. Garcia
Blanco, Jose L. Jimenez
Mellet, Carmen Ortiz
Fuentes, Jose
An efficient synthesis of macrocyclic ligands incorporating two α,α'-trehalose subunits linked through the primary C-6,6' positions by means of 1,3-thiourea spacers is reported; the Z/E configuration of the N-C(=S) bonds is governed by intramolecular hydrogen bonding as well as steric factors.
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