Activation Parameters for the Reaction of Phenylchloro Carbene with Pyridine, Tri-n-butyltin Hydride, and Triethylsilane; Evidence Against the Need to Invoke Reversibly Formed Complexes in the Reaction of This Carbene with Olefins

DOI: 10.1016/S0040-4039(00)99458-9

Source and publish data:

Tetrahedron Letters p. 1335 - 1338 (1989)

Update date:2022-08-11

Topics:

Authors:

Jackson, James E.

Soundararajan, N.

Platz, Matthew S.

Doyle, Michael P.

Liu, Michael T. H.

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Article abstract of DOI:10.1016/S0040-4039(00)99458-9

The activation energies for reaction of phenylchloro carbene with pyridine, tri-n-butyl-tin hydride and triethylsilane are reported.The data argues against reversibly formed complexes in the reaction of this carbene with olefins.

Full text of DOI:10.1016/S0040-4039(00)99458-9

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