Activation Parameters for the Reaction of Phenylchloro Carbene with Pyridine, Tri-n-butyltin Hydride, and Triethylsilane; Evidence Against the Need to Invoke Reversibly Formed Complexes in the Reaction of This Carbene with Olefins

DOI: 10.1016/S0040-4039(00)99458-9

Source and publish data:

Tetrahedron Letters p. 1335 - 1338 (1989)

Update date:2022-08-11

Topics:

Authors:

Jackson, James E.

Soundararajan, N.

Platz, Matthew S.

Doyle, Michael P.

Liu, Michael T. H.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)99458-9

The activation energies for reaction of phenylchloro carbene with pyridine, tri-n-butyl-tin hydride and triethylsilane are reported.The data argues against reversibly formed complexes in the reaction of this carbene with olefins.

Full text of DOI:10.1016/S0040-4039(00)99458-9

Products guided by the article

Product name:Benzene, (1-chloro-2,2,3,3-tetramethylcyclopropyl)-

Cas No:3141-40-0

R&D Labs maybe for 3141-40-0

Arromax Pharmatech Co.,Ltd

website:http://www.arromax.com

Contact:+86-0512-62959601 skype:aimmezhang

Address:Suite 401, Bldg A3, 218 Xinghu St.Suzhou Industrial Park 215123, P.R. China
Shenyang NovPharm Technology Co., Ltd.

Contact:.+86-24-24165786

Address:Room 306, Hongjin Mansion, No. 36-1, Wanliutang Rd., Shenhe District, Shenyang, Liaoning, P.R.C.
Changzhou Ansciep Chemical Co.,Ltd.

Contact:+86 519 8630 5871

Address:A-710 Boan International, 8 East Guangdian Road,Wujin,Changzhou
Tangshan Moneide Trading Co., Ltd.

Contact:+86-315-8309571

Address:2-7-420 Jidong Building Materials Commercial Center, Tangshan, Hebei, 064000 China
Xi'an Kaixiang Photoelectric Technology Co., Ltd

website:http://www.kxmaterials.com/

Contact:86-29-15991651477

Address:Building 6, Biopharmaceutical Industry R&D Cluster Base, No. 16, Caotang 4th Road, Caotang Science and Technology Industrial Base, High-tech Zone, Xi'an City, Shaanxi Province, China

Relevant to this article

Discovery of antibiotic (E)-3-(3-carboxyphenyl)-2-(4-cyanostyryl)quinazolin-4(3 H)-one

Doi:10.1021/jacs.5b00056
(2015)
Luminescence and Relaxometric Properties of Heteropolymetallic Metallostar Complexes with Selectively Incorporated Lanthanide(III) Ions

Doi:10.1002/ejic.201500648
(2015)
N-Mannich bases of benzimidazole as a potent antitubercular and antiprotozoal agents: Their synthesis and computational studies

Doi:10.1080/00397911.2020.1725057
(2020)
Endo-Selectivity and Kinetic Control in Alkali Metal-NH3-NH4(1+) Reductions of Bicyclo<2.2.1>heptan-2-ones

Doi:10.1039/c39860001558
(1986)
Phenazine-based colorimetric and fluorescent sensor for the selective detection of cyanides based on supramolecular self-assembly in aqueous solution

Doi:10.1016/j.saa.2016.12.022
(2017)
Synthesis and application of dimeric Cinchona alkaloid phase-transfer catalysts: α,α′-bis[O(9)-allylcinchonidinium]-o, m, or p-xylene dibromide

Doi:10.1039/b102584h
(2001)

Article Doi